(N-Benzyl-N-ethyldithiocarbamato)di-tert-butylchloridotin(IV)
نویسندگان
چکیده
The Sn(IV) atom in the title diorganotin dithio-carbamate, [Sn(C(4)H(9))(2)Cl(C(10)H(12)NS(2))], is penta-coordinated by an asymmetrically coordinating dithio-carbamate ligand, a Cl and two C atoms of the Sn-bound tert-butyl groups. The resulting C(2)ClS(2) donor set defines a coordination geometry inter-mediate between square pyramidal and trigonal bipyramidal with a slight tendency towards the former. In the crystal structure, C-H⋯π contacts link centrosymmetrically related mol-ecules into dimeric aggregates.
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Di-n-butylbis(N-n-butyl-N-ethyldithiocarbamato-κS)tin(IV)
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